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gossypol biosynthesis
| State Icon | Reaction | EC-Number | Confidence maximal confidence score from EnzymeDetector | |
|---|---|---|---|---|
| S-adenosyl-L-methionine + desoxyhemigossypol <=> H+ + desoxyhemigossypol-6-methyl_ether + S-adenosyl-L-homocysteine |
2.1.1
|
–
|
||
| hemigossypol + O2 <=> gossypol + H2O |
1.10.3.2
laccase
|
–
|
||
| (2E,6E)-farnesyl_diphosphate <=> (+)-delta-Cadinene + diphosphate |
4.2.3.13
(+)-delta-cadinene synthase
4.2.3.97 (-)-delta-cadinene synthase |
–
– |
||
| desoxyhemigossypol-6-methyl_ether + O2 + H2O <=> hemigossypol-6-methyl_ether + H2O2 |
not assigned |
–
|
||
| desoxyhemigossypol + O2 + H2O <=> hemigossypol + H2O2 |
not assigned |
–
|
||
| hemigossypol-6-methyl_ether + O2 <=> gossypol-6,6''-dimethyl_ether + H2O |
1.10.3.2
laccase
|
–
|
||
| (+)-delta-Cadinene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 8-hydroxy-(+)-delta-cadinene + oxidized_[NADPH-hemoprotein_reductase] + H2O |
1.14.14
|
–
|
||
| 8-hydroxy-(+)-delta-cadinene <=> desoxyhemigossypol |
not assigned |
–
|
||